期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 441, 期 -, 页码 52-58出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2014.11.018
关键词
Knoevenagel condensation; Solvent-free reaction; Aldehydes; Active methylene compounds; Ni-Fe-HT
资金
- National Academy of Sciences (India)
Thermal decomposition of co-precipitated Ni-Fe-HT materials led to the formation a mesoporous Ni-Fe-HT catalyst and we have demonstrated here its active role as solid and active catalyst for the Knoevenagel condensation reaction of various aldehydes with active methylene compounds (R-CH2-CN, where R=CN or CO2Et). High product yields are obtained at moderate temperature under solvent-free conditions and the catalyst can be easily separated from the reaction mixture, simply by filtration and reused several times without a significant loss of its activity. Since these mesoporous metal oxides derived from the NiFe hydrotalcites, their basicity mediated abstraction of the acidic protons from the active methylene compounds was responsible for their catalytic activity under solvent-free conditions. (C) 2014 Elsevier Inc. All rights reserved.
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