期刊
JOURNAL OF CHEMICAL SCIENCES
卷 123, 期 1, 页码 47-54出版社
INDIAN ACAD SCIENCES
DOI: 10.1007/s12039-011-0103-6
关键词
Ionic Pd; carbon-carbon coupling; Heck reaction; Pd-ceria; heterogeneous catalysis
资金
- Department of Science and Technology (DST)
- Council of Scientific and Industrial Research (CSIR), New Delhi
Palladium substituted in cerium dioxide in the form of a solid solution, Ce-0.98 Pd-0.02 O-1.98 is a new heterogeneous catalyst which exhibits high activity and 100% trans-selectivity for the Heck reactions of aryl bromides including heteroaryls with olefins. The catalytic reactions work without any ligand. Nano-crystalline Ce-0.98 Pd-0.02 O-1.98 is prepared by solution combustion method and Pd is in +2 state. The catalyst can be separated, recovered and reused without significant loss in activity.
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