期刊
ADVANCES IN PHYSICAL CHEMISTRY
卷 -, 期 -, 页码 -出版社
HINDAWI LTD
DOI: 10.1155/2011/907129
关键词
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资金
- National Science Foundation [NSF CHE06-51083]
- ARO [W911NF-08-1-0309]
- Office of Basic Energy Sciences [ERKCC61]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences
- Department of Energy's Office of Biological and Environmental Research
- National Center for Computational Sciences at Oak Ridge National Laboratory
- National Energy Research Scientific Computing Center - Office of Science of the U. S. Department of Energy
The advances in spectroscopy and theory that have occurred over the past two decades begin to provide detailed in situ resolution of the molecular transformations that occur at both gas/metal as well as aqueous/metal interfaces. These advances begin to allow for a more direct comparison of heterogeneous catalysis and electrocatalysis. Such comparisons become important, as many of the current energy conversion strategies involve catalytic and electrocatalytic processes that occur at fluid/solid interfaces and display very similar characteristics. Herein, we compare and contrast a few different catalytic and electrocatalytic systems to elucidate the principles that cross-cut both areas and establish characteristic differences between the two with the hope of advancing both areas.
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