期刊
E-JOURNAL OF SURFACE SCIENCE AND NANOTECHNOLOGY
卷 10, 期 -, 页码 575-577出版社
SURFACE SCI SOC JAPAN
DOI: 10.1380/ejssnt.2012.575
关键词
X-ray absorption spectroscopy; X-ray emission; Manganese
资金
- Global Centers of Excellence Program International Center for Integrated Research and Advanced Education in Materials Science
- Ministry of Education, Culture, Sports, Science and Technology of Japan
- Japan Science and Technology Agency's CREST program
- JPSJ KAKENHI [22540344]
- [2008B1222]
- [2009B1017]
- [2009B1210]
- [19GS0207]
We investigated the electronic structure of LaMn3B4O12 (LMVO) and LaMn3B4O12 (LMCO) by X-ray absorption spectroscopy (XAS) and resonant X-ray emission spectroscopy (RXES) measurements around Mn 2p edges. The Mn 2p-XAS spectra showed that the Mn valence is trivalent for LMCO and divalent for LMVO. These results indicate that the A'-site can accommodate not only Jahn-Teller ions but also non-Jahn-Teller ions. The Mn 2p-RXES spectra showed the difference of the hybridization between Mn-3d and O-2p orbitals. According to theoretical calculation results, LMCO is candidates for the negative charge transfer energy compound.
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