期刊
INTERNATIONAL JOURNAL OF CHEMICAL ENGINEERING
卷 2012, 期 -, 页码 -出版社
HINDAWI LTD
DOI: 10.1155/2012/750162
关键词
-
资金
- NSERC Canada
- MITACS
There are two classes of mixing sensitive reactions: competitive-consecutive and competitive-parallel. The yield of desired product from these coupled reactions depends on how fast the reactants are brought together. Recent experimental results have suggested that themixing effectmay depend strongly on the stoichiometry of the reactions. To investigate this, a 1D, dimensionless, reactiondiffusion model at the micromixing scale was developed. Assuming constant mass concentration and mass diffusivities, systems of PDE's were derived on a mass fraction basis for both types of reactions. Two dimensionless reaction rate ratios and a single general Damkohler number emerged from the analysis. The resulting dimensionless equations were used to investigate the effects of mixing, reaction rate ratio, and reaction stoichiometry. As expected, decreasing either the striation thickness or the dimensionless rate ratio maximizes yield, the reaction stoichiometry has a considerable effect on yield, and all three variables interact strongly.
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