期刊
ACS APPLIED MATERIALS & INTERFACES
卷 7, 期 34, 页码 18930-18936出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b05648
关键词
TADF; charge transfer transition; carbazole; pyridine; carbonitrile; blue emitter; OLEDs
资金
- National Natural Science Foundation of China [51373190]
- Beijing Nova Program [Z14110001814067]
- Chinese Academy of Sciences, P. R. China [YE201133]
A novel blue thermally activated delayed fluorescence (TADF) emitter, CPC (2,6-di(9H-carbazol-9-yl)-4-phenylpyridine-3,5-dicarbonitrile), was designed and synthesized. By directly linking carbazole (to serve as electron-donor) and pyridine-3,5-dicarbonitrile (to serve as electron-acceptor), and distributing cyanogroups and carbazole groups at the para-position of pyridine core, CPC successfully achieves an extremely small singlet-triplet splitting and fairish photoluminescence quantum yield, thus can act as the highly efficient blue TADF emitter. The optimized organic light-emitting diode (OLED) based on 13 wt % CPC doped in mCP (1,3-bis(9H-carbazol-9-yl)benzene) host exhibits maximum current efficiency, power efficiency, and external quantum efficiency of 47.7 cd A(-1), 42.8 lm W-1, and 21.2%, respectively, which are the best results in reported blue TADF-based devices up to date and even comparable with the best reported blue phosphorescent OLEDs.
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