期刊
INTERNATIONAL JOURNAL OF CHEMICAL ENGINEERING
卷 2014, 期 -, 页码 -出版社
HINDAWI LTD
DOI: 10.1155/2014/916913
关键词
-
资金
- National Basic Research Program of China (973 Program) [2011CB201202]
Resorcinol-formaldehyde resin polymer was used as raw material for preparation of carbon spheres. Samples were treated with CO2 flow at 850 degrees C by varying activation times. The CO2 activation granted better pore development of pore structure. The experimental data of CH4 adsorption as a function of equilibrium pressure was fitted by Langmuir and Dubinin-Astakhov (D-A) models. It was concluded that the high surface area and micropore volume of carbon spheres did unequivocally determine methane capacities. In addition, a thermodynamic study of the heat of adsorption of CH4 on the carbon spheres was carried out. Adsorption of CH4 on carbon spheres showed a decrease in the adsorption heat with CH4 occupancy, and the heat of adsorption fell from 20.51 to 12.50 kJ/mol at 298K and then increased to a little higher values at a very high loading (>0.70), indicating that CH4/CH4 interactions within the adsorption layer became significant.
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