期刊
RSC ADVANCES
卷 5, 期 125, 页码 103210-103217出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra22251f
关键词
-
资金
- Basque Government [IT-774-13, S-PC13UN018]
- Spanish Ministry of Economy and Competitiveness [CTQ2010-20703]
- University of the Basque Country [UFI QOSYC 11/12]
- University of the Basque Country (UPV/EHU)
An efficient catalyst system for the Pd-catalyzed aerobic oxidation of benzylic positions has been developed. The combination of palladium(II) acetate and 3,5-bis((1H-1,2,4-triazol-1-yl) methyl) benzoate ligand allows the selective oxidation at carbon adjacent to arene rings (primary and secondary benzylic alcohols, and other benzyl compounds) to provide the corresponding carbonyl and carboxy derivatives, employing molecular oxygen as oxidizing agent and a very low metal loading (10(-5) mol%).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据