期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 36, 页码 31095-31101出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b08783
关键词
smart nanofluids; associative cellulose nanocrystals; hydrophobic interaction; sol gel transition; nanofibrillar crystallinity
资金
- National Research Foundation of Korea (NRF) - Korea government (MSIP) [2008-0061891, 2016R1A2B2016148]
Cellulose fibrils, unique plant-derived semicrystalline nanomaterials with exceptional mechanical properties, have significant potential for rheology modification of complex fluids due to their ability to form a physically associated semiflexible fibrillary network. Here, we report new associative cellulose nanocrystals (ACNCs) with stress-responsive rheological behaviors in an aqueous solution. The surface-mediated living radical polymerization was employed to graft poly(stearyl methacrylate-co-2methacryloxyethyl phosphorylcholine) brushes onto the nanofibrils, and then 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation was conducted to produce nanoscale ACNCs in the aqueous solution. The ACNCs displayed interfibril association driven by the hydrophobic interaction that resulted in the formation of a nanofibrillar crystalline gel phase. We observed that the viscosity of the ACNC fluid showed reversible shear thinning and temperature-induced thickening in response to applied shear stress and thermal shock. Moreover, thanks to generation of a mechanically robust nanofibrillar crystalline gel network, the ACNC suspension showed extraordinary stability to changes in salinity and pH. These results highlighted that the interfibril hydrophobic association of ACNCs was vital and played an essential role in regulation of stimulireVonsive sol gel transitions.
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