期刊
出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jchromb.2014.11.026
关键词
Exhaled breath; INCAT; Monomethylalkanes; n-Alkanes; Needle trap
资金
- Research & Development Operational Program - ERDF [ITMS 26240220071, ITMS 26240220086, ITMS 26240220007]
- Slovak Research and Development Agency [APVV-0840-11, APVV-0416-10, APVV-0061-11]
A new arrangement of the INCAT (inside needle capillary adsorption trap) device with Carbopack X and Carboxen 1000 as sorbent materials was applied for sampling, preconcentration and injection of C-6-C-19 n-alkanes and their monomethyl analogs in exhaled breath samples. For the analysis both GC MS/MS and GC x GC-FID techniques were used. Identification of the analytes was based on standards, measured retention indices and selective SRM transitions of the individual isomers. The GC-MS/MS detection limits were in the range from 2.1 pg for n-tetradecane to 86 pg for 5-methyloctadecane. The GC x GC-FID detection limits ranged from 19 pg for n-dodecane to 110 pg for 3-methyloctane. (C) 2014 Elsevier B.V. All rights reserved.
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