期刊
CHEMCATCHEM
卷 10, 期 1, 页码 329-333出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201701133
关键词
alloys; hydrogenation; nanoparticles; palladium; rhodium
资金
- National Science Foundation [CHE-1505135]
- Welch Foundation [F-1738, F-1831]
- Division Of Chemistry [1505135] Funding Source: National Science Foundation
The chemistry of metastable RhPd alloys is not well understood, and well-characterized nanoparticle (NP) examples remain rare. Well-defined and near-monodisperse RhPd NPs were prepared in a simple one-pot approach by using microwave-assisted or conventional heating in reaction times as short as 30s. The catalytic hydrogenation activity of supported RhPd NP catalysts revealed that short synthesis times resulted in the most-active and most-stable hydrogenation catalysts, whereas longer synthesis times promoted partial Rh-Pd core-shell segregation. Relative to Rh NPs, RhPd NPs resisted deactivation over longer reaction times. Density functional theory (DFT) was employed to estimate the binding energies of H and alkenes on (111) Rh, Pd, and Rh0.5Pd0.5 surfaces. The DFT results concurred with experiment and concluded that the alkene hydrogenation activity trend was of the order Pd
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