期刊
BIORESOURCES
卷 13, 期 3, 页码 7137-7154出版社
NORTH CAROLINA STATE UNIV DEPT WOOD & PAPER SCI
DOI: 10.15376/biores.13.3.Zhang
关键词
5-Hydroxymethylfurfural; 2,5-Bis-(hydroxylmethyl) furan; Catalytic transfer hydrogenation; Biomass-based polymer
资金
- National Natural Science Foundation of China [21406208]
- Natural Science Foundation of Zhejiang Province [LY17C160008]
- Open Foundation of the Most Important Subjects in Colleges and Universities in Zhejiang Province [2015YXQN13]
- Zhejiang Provincial Top Key Academic Discipline of Chemical Engineering and Technology of Zhejiang Sci-Tech University [YR2015005]
- 521 Talent Cultivation Program of Zhejiang Sci-Tech University [11110132521309]
To meet increasing demands for alternatives to fossil-based chemicals, environment-friendly and renewable energy materials are of great importance. Biomass-derived 2,5-bis-(hydroxylmethyl)furan (BHMF) has the potential to partly substitute petroleum-based aromatic diols during polymerization. This paper summarizes recent research on the synthesis of BHMF by the reaction of hydrogen from biomass-based 5-hydroxymethylfurfural through different reduction routes, including the Cannizzaro reaction, catalytic hydrogenation, and catalytic transfer hydrogenation. Applications of BHMF as a direct material and intermediate in fabricating polyurethane, self-healing materials, resins, and more, which utilize ring-opening, double-bond addition, and oxidation reactions, are discussed briefly. Additionally, the challenges and opportunities in the formation and application of BHMF in the future are discussed.
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