期刊
POLYMER CHEMISTRY
卷 9, 期 47, 页码 5566-5571出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8py01256c
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资金
- National Natural Science Foundation of China [21774103, 21364013]
- Youth Science and Technology Innovation Team of SWPU [2017CXTD05]
A novel octylphosphonic acid (OPA)-catalyzed, high-efficiency, three-component polymerization system involving benzoxazines, odorless isocyanides, and water was developed to synthesize polyamide derivatives with satisfactory molecular weights. This polymerization system showed the advantages of atom-economy, wide substrate scope, short reaction time (6 h), atmosphere-insensitivity, and mild reaction conditions (metal-free catalyst and room temperature).
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