期刊
ORGANIC CHEMISTRY FRONTIERS
卷 5, 期 23, 页码 3476-3482出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo01044g
关键词
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资金
- 1000-Youth Talents Plan
- National Natural Science Foundation of China [21772183]
- Fundamental Research Funds for the Central Universities [WK2060190086]
- University of Science and Technology of China
In this protocol, we developed a reductive strategy for 1,2-iminoacylation of alkenes. Under the catalysis of the Ni-biquinoline system, various oxime esters incorporating a pendant terminal olefinic unit were successfully reacted with acid chlorides or anhydrides as electrophilic acylating reagents in the presence of Zn as a reductant, furnishing a series of pyrrolines in moderate to excellent yields. This reaction is distinguished by safe and mild reaction conditions that avoid the use of CO gas as a carbonyl source, pregenerated organometallics and strong bases as reaction additives.
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