Fractional purification and bioconversion of hemicelluloses

Hemicelluloses are types of plant cell wall polysaccharides, and the world's second most abundant renewable polymers after cellulose in lignocellulosic materials. They represent a type of hetero-polysaccharide with complex structure containing glucose, xylose, mannose, galactose, arabinose, rhamnose, glucuronic acid, and galacturonic acid in various amounts, depending on the source. Hemicelluloses are usually bonded to other cell-wall components such as cellulose, cell-wall proteins, lignin, and phenolic compounds by covalent and hydrogen bonds, and by ionic and hydrophobic interactions. This paper provides a review on hemicelluloses from lignocellulosic materials, especially in regard to their isolation and purification methods, and bioconversion. Current isolation and purification strategies are summarized, including: alkali peroxide extraction, organic solvent extraction, steam explosion, ultrasound-assisted extraction, microwave-assisted extraction, column chromatography, and membrane separation. In addition, the bioconversion of hemicelluloses including pretreatment, enzymatic hydrolysis, and fermentation are discussed. (C) 2012 Elsevier Inc. All rights reserved.