期刊
JOULE
卷 2, 期 5, 页码 902-913出版社
CELL PRESS
DOI: 10.1016/j.joule.2018.01.017
关键词
-
资金
- National Natural Science Foundation of China [21622303, 21373060]
- National Key Research and Development Plan [2016YFB0901500]
Low-temperature operation is a great challenge facing rechargeable batteries, and insufficient ionic conductivity and freezing of electrolyte are generally considered as the main reasons for this issue. Herein, an ethyl acetate-based electrolyte with a sufficient ionic conductivity of 0.2 mS cm(-1) at the ultra-low temperature of -70 degrees C is first used to fabricate intercalation compounds-based Li-ion batteries (LIBs) and an organic electrodes-based rechargeable battery, respectively, to clarify their low-temperature behavior- It is demonstrated that the LIBs cannot work at -70 degrees C because of the sluggish desolvation of Li+. However, the rechargeable battery using organic electrodes can work well at such low temperature and retains similar to 70% of capacity at room temperature, owing to the fast kinetics of charge storage on the surface groups or in the large interstitial space of organic solids. These results indicate a new way for developing low-temperature batteries.
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