期刊
CHINESE JOURNAL OF CATALYSIS
卷 39, 期 7, 页码 1167-1179出版社
SCIENCE PRESS
DOI: 10.1016/S1872-2067(18)63057-8
关键词
Covalent organic framework; Organic porous material; Catalyst; Catalyst support; Heterogeneous catalysis
资金
- National Natural Science Foundation of China [21473196, 21406215]
- State Key Laboratory of Fine Chemicals, Dalian University of Technology [KF1415]
- Dalian Institute of Chemical Physics, Chinese Academy of Sciences [DICP_M201401]
Covalent organic frameworks (COFs), established as an emerging class of crystalline porous polymers with high surface area, structural diversity, and designability, attract much interest and exhibit potential applications in catalysis. In this review, we summarize the use of COFs as a versatile platform to develop heterogeneous catalysts for a variety of chemical reactions. Catalytic COFs are categorized in accordance with the types of active sites, involving single functional active sites, bifunctional active sites, and metal nanoparticles (NPs) embedded in pores. Special emphasis is placed on the deliberate or incidental synthesis strategies, the stability, the heterogeneity, and the shape/size selectivity for COF catalysis. Moreover, a description of the application of COFs as photocatalysts and electrocatalysts is presented. Finally, the prospects of COFs in catalysis and remaining issues in this field are indicated. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
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