期刊
ENERGY STORAGE MATERIALS
卷 13, 期 -, 页码 134-141出版社
ELSEVIER
DOI: 10.1016/j.ensm.2018.01.005
关键词
Self-template; Doped graphene; Multi-dopants; Sodium-ion batteries; Redox processes
资金
- National Natural Science Foundation of China [51572129, 51602157, 51772154]
- National Natural Science Foundation of Jiangsu Province [BK20170036, BK20160830]
- International S & T Cooperation Program of China [2016YFE0111500]
- Fundamental Research Funds for the Central Universities [30915011204, 30916011353]
Heteroatom-doped graphene materials are one of the most promising electrode materials in energy-related realms. In this work, highly doped graphene nanosheets with tunable N and S codopants (NS-GNS) are prepared via a facile one-pot method and investigated in sodium-ion batteries (SIBs). During the pyrolysis, the starting materials can form planar sacrificial-templates that serve for the growth of 2D graphene structure and further in-situ convert into rich N and S dopant species, successfully solving the general challenge of high doping level of multi-heteroatoms into the graphene matrix. Integrating the abundant N, S and O-induced electrochemical redox centers at different potentials, the NS-GNS electrode demonstrates a high reversible capacity of around 400 mAh g(-1). Particularly, the ultra-long cycle life of 10,000 cycles and good rate capability of the present NS-GNS electrode make it promising for practical application in large-scale energy storage. This work guilds a direction toward redox-enhanced graphene materials with multi-dopants for energy storage and meanwhile provides a low-cost and scalable method for the mass production of well-defined graphene materials with tunable properties.
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