Structural hybridization of ternary (0D, 1D and 2D) composites as anodes for high-performance Li-ion batteries

We report herein on a novel structural hybridization strategy to synthesize a ternary composite (Fe, Co)(3)O-4/Co3O4/rGO using a facile hydrothermal method for high-performance lithium-ion batteries (LIBs). In the asfabricated hybrid structure, high-capacity (Fe, Co)(3)O-4 sub-microparticles (zero-dimension) and Co3O4 nanorods (one-dimension) are composited with highly conductive network of reduced graphene oxide (rGO) nanosheets (two-dimension). Benefiting from the unique architecture, the volume expansion of (Fe, Co)(3)O-4, Co3O4 during charging/ discharging and their direct exposure to the electrolyte have been effectively alleviated by the spatially confining effects of rGO nano-sheets. On the other hand, the intrinsic wrinkle morphology of graphene nano-sheets was alleviated by the nano-rods support, leading to enhanced transportation mobility of electrons and ions. Furthermore, the formed hierarchical pores effectively increase the reaction sites and kinetics. As a result, the as-built electrode of the ternary composite shows remarkably cycling stability (1668.5 mAh g(-1) for the first cycle and 80.97% capacity retention after 500 cycles at 1 A g(-1)) and rate capability (341.6 mAh g(-1) at 10 A g(-1)), which are much superior to those of binary composites. The newly fabricated ternary composites as well as the structural hybridization strategy show great potentials in energy storage applications.