期刊
CHEMPHOTOCHEM
卷 2, 期 1, 页码 27-33出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cptc.201700172
关键词
electrochemiluminescence; energy transfer; europium; iridium; lanthanides
资金
- Australian Research Council [DP150102741]
A new class of electrochemiluminescent (ECL) system is reported in which a heterobimetallic array is used to facilitate electrochemically initiated lanthanide emission, following energy transfer from an ECL-active donor. Spectroscopic measurements are used to probe the efficiency, rate and mechanism of the energy-transfer process in two bimetallic systems with differing donor energies. Non-optical sensitization of the luminescence from lanthanide ions opens up exciting new possibilities for the development of ECL probes with sharper emission peaks and a greater variety of emission colours.
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