期刊
BIORESOURCE TECHNOLOGY
卷 137, 期 -, 页码 311-317出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2013.03.105
关键词
Hydrogenolysis; Cellulose; Methanol; C4-C7 alcohols; CuO-based bi-functional catalyst
资金
- Major State Basic Research Development Program of China (973 Project) [2011CB200906]
- National Key Technology R&D Program of China [2010BAC66B01]
- National Natural Science Foundation of China [21161140329]
- National High Technology Research and Development Program of China (863) [SS2012AA021402]
- Hundred Talents Program of the Chinese Academy of Sciences
This work demonstrates the efficient hydrogenolysis of cellulose to C4-C7 alcohols and gas products (reaction 1) by coupling it with the reforming reaction of methanol (reaction 2) over bi-functional CuO-based catalysts. In this process, the CuO-based catalysts catalyze both the reactions 1 and 2, and the in situ regenerated H-2 in the reaction 2 is used for the reaction 1. A series of CuO-MO/Al2O3 (M = Ce, Mg, Mn, Ni, Zn) catalysts were prepared by the co-precipitation method. Among these catalysts, CuO-ZnO/Al2O3 exhibited the highest activity to generate a high cellulose conversion of 88% and a high C4-C7 alcohols content above 95% in the liquid products. The CuO-ZnO/Al2O3 catalyst was stable under the reaction conditions and reusable after 4 runs. This work provides a cost-effective route to convert abundant renewable cellulose to liquid fuels. (C) 2013 Elsevier Ltd. All rights reserved.
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