期刊
BIORESOURCE TECHNOLOGY
卷 102, 期 6, 页码 4402-4409出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2010.12.117
关键词
Chitosan; Carbon nanotube; Sodium dodecyl sulfate; Surfactant; Adsorption
资金
- Ministry of Education, Science and Technology [2009-0079636]
The adsorption performance of chitosan (CS) hydrogel beads (CSBs) generated by sodium dodecyl sulfate (SOS) gelation with multi-walled carbon nanotube (CNT) impregnation was investigated for Congo red removal as a model anionic dye. CNT-impregnated CSBs were prepared by four different strategies for dispersing CNTs: (a) in CS solution (CSBN1), (b) in SOS solution (CSBN2), (c) in CS solution containing cetyltrimethylammonium bromide (CTAB) (CSBN3), and (d) in SDS solution for gelation with CTAB-containing CS solution (CSBN4). It was observed from FE-SEM study that depending on nature of CNT dispersion, CNTs were found on the outer surface of CSBN2 and CSBN4 only. The adsorption capacity of the CSBs varied with the strategy used for CNT impregnation, and CSBN4 exhibited the highest maximum adsorption capacity (375.94 mg/g) from the Sips model. The lowest Sips maximum adsorption capacity by CSBN3 (121.07 mg/g) suggested significant blocking of binding sites of CS by CNT impregnation. (C) 2011 Elsevier Ltd. All rights reserved.
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