期刊
BIORESOURCE TECHNOLOGY
卷 101, 期 17, 页码 6836-6842出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2010.03.112
关键词
Gelatin; Chestnut tannin; Solubility; Transition temperatures; Mechanical properties
资金
- Basque Country Government [IT-365-07, SAIOTEK09]
In order to reduce pollution caused by traditional non-biodegradable plastic films, renewable raw materials from plants and wastes of meat industries have been employed in this work. A hydrolysable chestnut-tree tannin was used for gelatin modification. Films of gelatin and gelatin-tannin were obtained by casting at room conditions. Transition temperatures of both gelatin and gelatin-tannin systems were determined by differential scanning calorimetry (DSC). Glass transition temperatures of modified gelatin occurred at higher temperatures than for neat gelatin. Enthalpy and temperature of helix-coil transition decreased when tannin content increased due to variations in the helical structure of gelatin as a consequence of tannin presence in agreement with X-ray analysis. Mechanical and thermal behaviour varied as a function of the content of tannin, showing optimum values for films modified with 10 wt% tannin. The transparency of films was maintained after modification with tannin. Solubility and swelling tests of the films revealed that the presence of tannin reduced the water affinity of gelatin. (C) 2010 Elsevier Ltd. All rights reserved.
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