Adsorption of raw and treated by membranes fermentation brines from table olives processing for phenolic compounds separation and recovery

BACKGROUNDFermentation brines from table olive processing are effluents characterized by very high salinity and high organic matter concentration, which includes phenols of high value as hydroxytyrosol that is used by pharmaceutical and cosmetic industries. RESULTSIn this work the adsorption with a phenols-selective resin (MN200) of fermentation brine (raw and pre-treated by ultrafiltration or by ultrafiltration plus nanofiltration) has been studied. The study included the adsorption and desorption process, and the useful life of the resin was evaluated. Results indicated that resin MN200 above 20gL(-1) yielded phenols separation efficiencies higher than 90%. However, the adsorption of nanofiltrated effluent separated phenols more selectively. Adsorption kinetics fitted properly to a pseudo-second-order kinetics and the Langmuir isotherm correctly model the adsorption process. Results of the intra-particle diffusion model show that the pore diffusion is not the only rate limiting step. Desorption was carried out with ethanol. More than 85% of phenolic compounds were recovered. The use of the resin during ten cycles showed that the nanofiltrated effluent increased the useful time of the resin. CONCLUSIONThe MN200 resin was a viable alternative to phenols removing and further recovering, in FTOP effluents. The optimal conditions were obtained for nanofiltrated effluents. (c) 2015 Society of Chemical Industry