期刊
JOURNAL OF CHEMICAL PHYSICS
卷 143, 期 7, 页码 -出版社
AIP Publishing
DOI: 10.1063/1.4928692
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资金
- ANR [ANR2010 BLANC040501]
We present photo-fragmentation electronic spectra of the simplest protonated aromatic molecules, protonated benzene and toluene, recorded under medium resolution conditions and compared with the photo-fragmentation spectrum of protonated pyridine. Despite the resolution and cold temperature achieved in the experiment, the electronic spectra of protonated benzene and toluene are structure-less, thus intrinsically broadened. This is in agreement with the large geometrical changes and the fast dynamic toward internal conversion predicted by ab initio calculations for protonated benzene [Rode et al., J. Phys. Chem. A 113, 5865-5873 (2009)]. (C) 2015 AIP Publishing LLC.
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