期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 6, 期 42, 页码 21225-21230出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta08590k
关键词
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资金
- Natural Science Foundation of China [51772008]
- National Key Research and Development Program of China [2017YFA0206701]
- National Program for Support of Top-notch Young Professionals
- Changjiang Scholar Program
Boron and nitrogen co-doped graphene (BCN) nanotubes have tremendous properties for energy storage devices. Herein, we first report a BCN nanotubes architecture entangled on a three dimensional (3D) melamine foam derived carbon skeleton with high surface area, hierarchical porosity and heteroatoms (B, C, N) extant. Having such efficacious properties, 3D-BCN-950 (calcinated under 950 degrees C) exhibited excellent capacitance of 344 F g(-1) at a current density of 1 A g(-1). Furthermore, 3D-BCN-950 nanotubes are utilized as electrodes in a symmetric and negative electrode in asymmetric hybrid supercapacitors. The symmetric supercapacitor presented a high energy density of 19.8 W h kg(-1) and elevated power density of 5074 W kg(-1), the asymmetric supercapacitor also demonstrated a high energy density of 72 W h kg(-1) and power density of 22 732 W kg(-1). These results indicate the as-synthesized heteroatoms doped graphene nanotubes architecture could be a potential negative electrode materials for the fabrication of future high energy density hybrid supercapacitors.
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