4.7 Article

Iron-catalyzed synthesis of cyclopropanes by in situ generation and decomposition of electronically diversified diazo compounds

期刊

CHEMICAL COMMUNICATIONS
卷 54, 期 94, 页码 13256-13259

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07060a

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资金

  1. Natural Science and Engineering Research Council of Canada (NSERC) [RGPIN-06438]
  2. Canada Foundation for Innovation Leaders Opportunity Funds [227346]
  3. Canada Research Chair Program [CRC-227346]
  4. FRQNT Centre in Green Chemistry and Catalysis (CGCC) Strategic Cluster [RS-171310]
  5. Universite de Montreal

向作者/读者索取更多资源

The modular synthesis of a variety of trans 1,2-disubstituted cyclopropanes in a safe and user-friendly one-pot iron-catalyzed cyclopropanation reaction is described. Easily synthesized N-nosylhydrazones are used as diazo precursors, allowing the in situ generation of electron-rich diazo compounds under mild reaction conditions and their direct participation in the cyclopropanation reaction.

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