期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 91, 页码 12844-12847出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc05210g
关键词
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资金
- Natural Science Foundation of China [21571096, 21773275, 21873044]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB17000000]
- Science and Technology Innovation Commission of Shenzhen Municipality [JCYJ20160301114634613, JCYJ20170817104715174]
A complex [Au(NHC)(2)][Au(C?N)(2)] double salt exhibits polymorphic crystalline structures with distinct phosphorescence and variations at AuAu distances and ligand-ligand torsion angles. This serves as a model system correlating aurophilicity and low-energy charge-transfer electronic transitions and helps to understand the thermochromism and mechanochromism of the gold(i) complexes.
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