期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 92, 页码 13022-13025出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc08328b
关键词
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Catalytic cross-dehydrogenative coupling of heteroarenes with thiophenols and phenothiazines has been developed under mild and environmentally benign reaction conditions. For the first time, NOx+ was applied for catalytic C-S and C-N bond formation. A comprehensive scope for the C-H/S-H and C-H/N-H cross-dehydrogenative coupling was demonstrated with >60 examples. The sustainable cross-coupling conditions utilize ambient oxygen as the terminal oxidant, while water is the sole by-product.
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