期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 3, 页码 738-743出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201710618
关键词
heterocycles; iminyl radicals; N-centered radicals; nitriles; photoredox catalysis
资金
- NNSFC [21472058, 21472057, 21622201, 21232003]
- Science and Technology Department of Hubei Province [2016CFA050, 2017AH047]
- Program of Introducing Talents of Discipline to Universities of China (111 Program) [B17019]
A room-temperature, visible-light-driven N-centered iminyl radical-mediated and redox-neutral C-C single bond cleavage/radical addition cascade reaction of oxime esters and unsaturated systems has been accomplished. The strategy tolerates a wide range of O-acyl oximes and unsaturated systems, such as alkenes, silyl enol ethers, alkynes, and isonitrile, enabling highly selective formation of various chemical bonds. This method thus provides an efficient approach to various diversely substituted cyano-containing alkenes, ketones, carbocycles, and heterocycles.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据