期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 4, 页码 891-897出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201704335
关键词
asymmetric borylation; chiral NHC ligand; copper catalysts; metathesis
资金
- National Science Centre (Poland) [DEC-2012/04/A/ST5/00594]
- European Union from the European Regional Development Fund under the Operational Programme Innovative Economy
Highly stereoselective conjugate beta-borylation, using a new chiral NHC-based copper catalyst, has been achieved. The chiral NHC copper complex was prepared in gram scale and showed high enantioselectivity and activity (up to 10000 turnovers at 100 ppm of catalyst loading). This method was employed in the synthesis of a chiral beta-borylated ester from simple unconjugated alkenes though an unprecedented one-pot cross metathesis-asymmetric borylation sequence.
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