期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 5, 页码 1193-1197出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201704661
关键词
in situ XRD; nanosheets; reaction mechanism; sodium ion batteries; titanium diselenide
资金
- Australian Research Council (ARC) DECRA Grant [DE160100596]
- ARC [DP160102627]
- AIIM FOR GOLD Grant
- National Natural Science Foundation of China [NSFC-51722105]
- Fundamental Research Funds for the Central Universities [2016QNA4007]
Materials with sheet-like morphologies are highly desirable candidates for energy storage and conversion applications, due to the confined atomic thickness and high surface area, which would largely improve the electrochemical reaction kinetics. In this work, the sodium storage performance of TiSe2 nanosheets and corresponding sodiation/desodiation reaction mechanism are studied for the first time. TiSe2 nanosheets are readily exfoliated from bulk TiSe2 after quick ultrasonication or grinding. The TiSe2 nanosheets exhibit a reversible capacity of 147 mAhg(-1) at 0.1 Ag-1, and show excellent rate capability with a capacity of 103 mAhg(-1) at an ultra-high current density of 10.0 Ag-1. The combined in situ XRD and ex-situ HRTEM results suggest that sodium storage in TiSe2 is achieved through a multistep intercalation/deintercalation mechanism. Besides, TiSe2 might be a promising 2D nanomaterial platform for other energy and electronic applications due to its easy exfoliation and unique physicochemical properties.
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