期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 1, 页码 203-207出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201710136
关键词
amino acids; arylation; palladium; peptides; triazoles
资金
- DFG
- CSC
- Alexander von Humboldt foundation
Secondary C(sp(3))-H arylations were accomplished by palladium catalysis with triazoles as peptide bond isosteres. The unique power of this approach is highlighted by the possibility of achieving secondary C(sp(3))-H functionalizations on terminal peptides as well as the unprecedented positional-selective C(sp(3))-H functionalization of internal peptide positions, setting the stage for modular peptide late-stage diversification.
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