期刊
ACS OMEGA
卷 3, 期 2, 页码 2329-2339出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.8b00043
关键词
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资金
- European Research Council (ERC) [StG 2012-306826]
- Networking Research Center on Bioengineering, Biomaterials, and Nanomedicine (CIBER-BBN)
- Generalitat de Catalunya [2014-SGR-17]
- Spanish Ministry of Economy and Competitiveness through the project FANCY [CTQ2016-80030-R]
- Spanish Ministry of Economy and Competitiveness through the Severo Ochoa Programme for Centers of Excellence in RD [SEV-2015-0496]
- Materials Science Program
- FPU
Organic semiconductors (OSCs) are promising materials for costeffective production of electronic devices because they can be processed from solution employing high-throughput techniques. However, small-molecule OSCs are prone to structural modifications because of the presence of weak van der Waals intermolecular interactions. Hence, controlling the crystallization in these materials is pivotal to achieve high device reproducibility. In this perspective article, we focus on controlling polymorphism and morphology in small-molecule organic semiconducting thin films deposited by solution-shearing techniques compatible with roll-to-roll systems. Special attention is paid to the influence that the different experimental deposition parameters can have on thin films. Further, the main characterization techniques for thin-film structures are reviewed, highlighting the in situ characterization tools that can provide crucial insights into the crystallization mechanisms.
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