期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 165, 期 14, 页码 A3292-A3298出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0291814jes
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资金
- University of Buenos Aires
- CONICET
- ANPCyT PICT 2014 [3654]
The spontaneous electrochemical extraction of lithium chloride from natural brine of high altitude salt flats in Northwest Argentina and recovery in a dilute electrolyte is demonstrated in two experiments: i) a highly selective LiMn2O4 insertion cathode and polypyrrole anion selective anode (salt capturing) and ii) an LiMn2O4 anode and lithium deficient Li-1-xMn(2)O(4) cathode separated by anion selective membrane (selective ion exchange). The entropy driven transfer of LiCl from concentrated brine to a dilute recovery electrolyte has been experimentally studied by ion pumping and the LiCl activity measured in natural brine. (C) 2018 The Electrochemical Society.
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