期刊
ADVANCED FUNCTIONAL MATERIALS
卷 28, 期 15, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201705763
关键词
cesium doping; hysteresis; mesoporous TiO2; passivation; perovskite solar cells; photovoltaics
类别
资金
- Swiss National Science Foundation
- ERC Proof of concept grant PRINTSolar
- SNSF NRP70 Energy Turnaround
- European Union's Horizon research and innovation program through an FET Open research and innovation action [687008]
- King Abdulaziz City for Science and Technology (KACST)
Rapid extraction of photogenerated charge carriers is essential to achieve high efficiencies with perovskite solar cells (PSCs). Here, a new mesoscopic architecture as electron-selective contact for PSCs featuring 40 nm sized TiO2 beads endowed with mesopores of a few nanometer diameters is introduced. The bimodal pore distribution inherent to these films produces a very large contact area of 200 m(2) g(-1) whose access by the perovskite light absorber is facilitated by the interstitial voids between the particles. Modification of the TiO2 surface by CsBr further strengthens its interaction with the perovskite. As a result, photogenerated electrons are extracted rapidly producing a very high fill factor of close to 80% a V-OC of 1.14 V and a PCE up to 21% with negligible hysteresis.
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