期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 16, 期 42, 页码 7792-7796出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob02094a
关键词
-
资金
- National Natural Science Foundation of China [NSF21472073, NSF21532001, NSF21772075]
A selective Friedel-Crafts acylation of indoles via an unusual cleavage of the amide C-N bond was achieved by triflic anhydride activation. This method offers rapid efficient access to high-biological-value 3-acylindoles, performs a series of scrupulous mechanistic studies and offers a strong courage that amide synthons can form new C-C bonds under transition-metal-free conditions.
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