期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 16, 期 43, 页码 8191-8195出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob01673a
关键词
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资金
- National Natural Science Foundation of China [21572203]
- Zhejiang Provincial Natural Science Foundation of China [LZ16B020001]
Heterocyclic compounds bearing 1,2,3-triazole scaffolds have found wide application both in medicinal chemistry and materials science. In this paper, rhodium(iii)-catalyzed triazole-directed alkylation reactions of arenes using diazo compounds as the alkylating agents are described. A number of polysubstituted arenes were provided from easily available materials in good yields under mild conditions. The reactions proceed via triazole-directed ortho C-H bond activation and subsequent carbene insertion originating from diazo compounds.
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