期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 16, 期 44, 页码 8565-8568出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob02431f
关键词
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资金
- Shandong Provincial Natural Science Foundation of China [ZR2016BQ31, ZR2016HM44, ZR2016JL009]
- Shandong Key Research Program of China [2017GSF218061]
- Major Program of Shandong Province Natural Science Foundation of China [ZR2017ZC0529]
- University of Jinan
Difluoromethylthiolation of aryldiazonium salts under photocatalytic conditions with a shelf-stable, easily prepared and inexpensive reagent, PhSO2SCF2H was described. A variety of difluoromethylthioethers were obtained utilizing aryldiazonium salts containing different functional groups. Aryldiazonium salts with a heteroarene moiety were tolerated. Fluorescence quenching experiments indicated that both oxidative and reductive quenching cycles occurred during this process.
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