期刊
CARBON ENERGY
卷 2, 期 1, 页码 122-130出版社
WILEY
DOI: 10.1002/cey2.16
关键词
bifunctional materials; hollow sphere; NiO; C nanoparticles; oxygen vacancies; rambutan-like structure
类别
资金
- Nanyang Technological University [M408050000]
- Singapore Ministry of Education Tier 1 program [2018-T1-001-051]
Transition metal oxides hold great promise for lithium-ion batteries (LIBs) and electrocatalytic water splitting because of their high abundance and high energy density. However, designing and fabrication of efficient, stable, high power density electrode materials are challenging. Herein, we report rambutan-like hollow carbon spheres formed by carbon nanosheet decorated with nickel oxide (NiO) rich in metal vacancies (denoted as h-NiO/C) as a bifunctional electrode material for LIBs and electrocatalytic oxygen evolution reaction (OER). When being used as the anode of LIBs, the h-NiO/C electrode shows a large initial capacity of 885mAhg(-1), a robust stability with a high capacity of 817mAhg(-1) after 400 cycles, and great rate capability with a high reversible capacity of 523mAhg(-1) at 10Ag(-1) after 600 cycles. Moreover, working as an OER electrocatalyst, the h-NiO/C electrode shows a small overpotential of 260mV at 10mAcm(-2), a Tafel slope of 37.6mVdec(-1) along with good stability. Our work offers a cost-effective method for the fabrication of efficient electrode for LIBs and OER.
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