期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 66, 页码 9561-9564出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03726e
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资金
- UGC
- CSIR, New Delhi
- CSIR-NP [GAP 0190, BSC0108]
The stereoselective sulfur-nitrogen difunctionalization (aminosulfonylation) across the alkyne framework in asynmode is accomplished using sodium sulfinates and azoles, in the presence of I-2/base. This strategy is applicable to a variety of terminal alkynes, sodium sulfinates, and azoles as reaction partners, affording (Z)-beta-amino vinylsulfones in good yields.
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