4.7 Article

Enantioselective gold(i)-catalyzed cyclization/intermolecular nucleophilic additions of 1,5-enyne derivatives

期刊

CHEMICAL COMMUNICATIONS
卷 56, 期 66, 页码 9457-9460

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc00914h

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  1. CSC (China Scholarship Council)
  2. Paris-Saclay University
  3. Ecole Polytechnique
  4. CNRS

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An enantioselective Au(i)-catalyzed cyclization/nucleophilic addition process is developed, starting from 1,5-enyne substrates. A broad scope of O-, N- and C-nucleophiles was introduced in order to provide the corresponding chiral cyclopentene derivatives in moderate to high yields and up to 96 : 4 enantiomeric ratio.

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