期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 20, 页码 3089-3092出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc10019a
关键词
-
资金
- NIH [R01GM101153]
Reaction of Fe-III(O-2 & x2d9;(-))(TPP) with 2,3-dimethylindole at -40 degrees C gives the ring-opened, dioxygenated N-(2-acetyl-phenyl)-acetamide product. The reaction was monitored in situ by low-temperature UV-vis and H-1 NMR spectroscopies. This work demonstrates that a discrete iron(iii)(superoxo) porphyrin is competent to carry out indole oxidation, as proposed for the tryptophan and indoleamine 2,3-dioxygenases.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据