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Editors' Choice-Review-Conductive Forms of MoS(2)and Their Applications in Energy Storage and Conversion

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出版社

ELECTROCHEMICAL SOC INC
DOI: 10.1149/1945-7111/abb34b

关键词

Electrocatalysis; Dichalcogenide; Energy Conversion; Energy Storage; Graphene; Surface modification

资金

  1. Natural Sciences and Engineering Research Council of Canada (NSERC)
  2. Canada First Research Excellence Fund project Global Water Futures

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Conductive forms of MoS(2)are important emerging 2D materials due to their unique combination of properties such as high electrical conductivity, availability of active sites in edge and basal planes for catalytic activity and expanded interlayer distances. Consequently, there has been a drive to find synthetic routes toward conductive forms of MoS2. Naturally occurring or synthetically grown semiconducting 2H-MoS(2)can either be converted into metallic 1T-MoS2, or various dopants may be introduced to modulate the electronic band gap of the 2H-MoS(2)phase and increase its conductivity. Chemical and electrochemical intercalation methods, hydrothermal and solvothermal processes, and chemical vapor deposition have all been developed to synthesize conductive MoS2. Conductive MoS(2)finds applications in energy storage devices, electrocatalytic reactions, and sensors. Here, we summarize a detailed understanding of the atomic structure and electronic properties of conductive MoS(2)which is crucial for its applications. We also discuss various fabrication methods that have been previously reported along with their advantages and disadvantages. Finally, we will give an overview of current trends in different applications in energy storage and electrocatalytic reactions in order to help researchers to further explore the applications of conductive MoS2.

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