4.7 Article

Rh-Catalyzed oxidative homo-coupling cyclization of 2,3-allenols to conjugated furylenones

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ORGANIC CHEMISTRY FRONTIERS
卷 8, 期 16, 页码 4432-4437

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qo00599e

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  1. National Natural Science Foundation of China [21690063, 21988101]

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An unexpected rhodium-catalyzed reaction has been reported for the synthesis of specific compounds with high efficiency, showing great potential for further research and applications.
An unexpected rhodium-catalyzed highly regio- and stereo-selective bimolecular nucleophilic oxyrhodation/insertion/1,4-Rh migration/beta-H elimination reaction of 2,3-allenols affording (2,5-dihydrofuran-3-yl)but-2(E)-en-1-one derivatives is reported. Optically active products may be prepared from optically active 2,3-allenols without obvious racemization. The synthetic potentials have been demonstrated.

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