4.6 Article

Rapid degradation behavior of encapsulated perovskite solar cells under light, bias voltage or heat fields

期刊

NANOSCALE ADVANCES
卷 3, 期 21, 页码 6128-6137

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1na00495f

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资金

  1. General Program of Science and Technology Development Project of Beijing Municipal Education Commission [KM202010005005]
  2. National Natural Science Foundation of China [62034001, 61922005, 61974008, 5207101067]
  3. Beijing Natural Science Foundation (BNSF) [JQ20027]
  4. Beijing Nova Program of Science and Technology [Z191100001119116]
  5. International Research Cooperation Seed Fund of Beijing University of Technology [2021B07]

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Stability is a key obstacle for the commercialization of perovskite solar cells as their power conversion efficiency approaches that of commercial solar cells. Rapid degradation in PCE is caused by external fields like bias voltage, light, and heat leading to ion migration. Experimental evidence shows that introducing layers like phenethylammonium iodide or poly-methyl methacrylate can inhibit ion migration and improve device stability.
When the power conversion efficiency (PCE) of perovskite solar cells (PSCs) rapidly approaches that of commercial solar cells, the stability becomes the most important obstacle for the commercialization of PSCs. Aside from the widely studied slow PCE degradation, the PSCs also show a unique rapid PCE degradation. Although the degradation due to oxygen and humidity can be avoided by encapsulation, that due to bias voltage, light and heat could not be effective suppressed and will lead to considerable degradation. Usually, the rapid PCE degradation is believed to be from ion migration. However, a systematic investigation is yet to be carried out. This work quantitatively and systematically investigated the relationships between external fields (bias voltage, light or heat), ion migration and device performance. By comparing the performance of reference PSCs after 90 min degradation under these fields, we conclude that (1) the electric field affects the spatial distribution of mobile ions; (2) the light field changes the mobile ion densities and drives the ion migration; (3) the heat field results in perovskite decomposition as well as changing the mobile ion densities. In addition to the analysis of the reference device, we experimentally proved that the improved device stability upon introducing phenethylammonium iodide (PEAI) or poly-methyl methacrylate (PMMA) layers originates from the inhibition of mobile ion density and migration.

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