Superiority of graphite coated metallic-nanoparticles over graphite coated insulating-nanoparticles for enhancing EMI shielding

In this work, we have used a single-step pyrolysis method in synthesizing carbonaceous materials at 800 degrees C and 1000 degrees C, using metal (Ni- or Mn-) acetylacetonate and toluene as precursors. We demonstrated that the pyrolysis synthesis temperature (T-P) and the choice of organometallic precursors affect the morphology and the microstructure of the carbonaceous materials. Namely, at low temperature (800 degrees C), the Ni(acac)(2) precursor leads to the formation of metallic-Ni catalysts for the growth of carbon nanotubes (CNTs), but at high temperature (1000 degrees C) this favors the growth of carbon globules (CG). In contrast, the Mn-(acac)(2) precursor leads to the formation of MnO-particles, and associated carbon globules at both the temperatures used. The electromagnetic interference (EMI) shielding effectiveness (SE) of the PVDF polymer based composite specimens prepared with the carbonaceous samples having a metallic Ni-core is found to be far superior than that obtained using the specimen with particles of the MnO-core. The observed contrast in SE behavior is shown to originate due to the size and metallic nature of the Ni-nanoparticles and the Ohmic conduction loss in these metallic particles over the loss due to interfacial polarization-based scattering of the insulating MnO nanoparticles present in the PVDF-based composite films. Hence, our study highlights the necessary synthesis parameters, and the importance of graphite coated metallic nanoparticles in designing highly efficient EMI shields.

Automated summary

In this study, carbonaceous materials were synthesized using a single-step pyrolysis method with metal acetylacetonates as precursors. The choice of precursor and synthesis temperature were found to influence the morphology and properties of the carbonaceous materials, particularly in relation to their effectiveness in electromagnetic interference shielding. Coated metallic nanoparticles were shown to significantly enhance the shield efficiency over insulating oxide particles.