Recent Progress and Future Prospects on All-Organic Polymer Dielectrics for Energy Storage Capacitors

With the development of advanced electronic devices and electric power systems, polymer-based dielectric film capacitors with high energy storage capability have become particularly important. Compared with polymer nanocomposites with widespread attention, all-organic polymers are fundamental and have been proven to be more effective choices in the process of scalable, continuous, and large-scale industrial production, leading to many dielectric and energy storage applications. In the past decade, efforts have intensified in this field with great progress in newly discovered dielectric polymers, fundamental production technologies, and extension toward emerging computational strategies. This review summarizes the recent progress in the field of energy storage based on conventional as well as heat-resistant all-organic polymer materials with the focus on strategies to enhance the dielectric properties and energy storage performances. The key parameters of all-organic polymers, such as dielectric constant, dielectric loss, breakdown strength, energy density, and charge-discharge efficiency, have been thoroughly studied. In addition, the applications of computer-aided calculation including density functional theory, machine learning, and materials genome in rational design and performance prediction of polymer dielectrics are reviewed in detail. Based on a comprehensive understanding of recent developments, guidelines and prospects for the future development of all-organic polymer materials with dielectric and energy storage applications are proposed.

Automated summary

With the development of advanced electronic devices and electric power systems, polymer-based dielectric film capacitors have become particularly important, with all-organic polymers being proven to be more effective choices in the process of scalable, continuous, and large-scale industrial production. Recent progress in the field has focused on strategies to enhance the dielectric properties and energy storage performances of all-organic polymers, with thorough studies on key parameters such as dielectric constant, dielectric loss, breakdown strength, energy density, and charge-discharge efficiency.