4.6 Article

Synthesis of Redox-Active Photochromic Phenanthrene Derivatives

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CHEMISTRY-A EUROPEAN JOURNAL
卷 28, 期 7, 页码 -

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202103755

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DFT calculations; dithienylethene; phenanthrene; photochromism; redox properties

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This article discusses the functionalization of a phenanthrene unit with methylthiophene units to achieve photochromic behavior, potentially leading to a new generation of organic field-effect transistors.
A phenanthrene unit has been functionalized by several methylthiophene units in order to bring it a photochromic behavior. These compounds were characterized by NMR, absorption and emission spectroscopies, theoretical calculations as well as cyclic voltammetry. The association of a phenanthrene group with a photochromic center could open the door to a new generation of organic field-effect transistors.

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