TADF-Sensitized Fluorescent Enantiomers: A New Strategy for High-Efficiency Circularly Polarized Electroluminescence

A promising strategy of thermally activated delayed fluorescence (TADF) sensitized circularly polarized luminescence (CPL) has been proposed for improving the electroluminescence efficiencies of circularly polarized fluorescent emitters. Compared with chiral TADF emitters which suffer from the dilemma of small Delta E-ST accompanied by small k(r), the TADF-sensitized CPL (TSCP) strategy using TADF molecules as sensitizers and CP-FL molecules as emitters might be the most promising method to construct high-performance circularly polarized organic light-emitting diodes (CP-OLEDs). Consequently, by taking advantage of the theoretically 100% exciton utilization of TADF sensitizers, especially, by designing CP-FL emitters with high PLQY, narrow FWHM and large g(lum) values, TSCP-type CP-OLEDs with excellent overall performances can be realized.

Automated summary

The TSCP strategy utilizes TADF molecules as sensitizers and CP-FL molecules as emitters to improve the electroluminescence efficiencies of circularly polarized fluorescent emitters, offering a promising method to construct high-performance circularly polarized organic light-emitting diodes. By designing CP-FL emitters with specific characteristics, TSCP-type CP-OLEDs with excellent overall performances can be realized.